Product ID:DART 151
MSDS Date:11/07/1989
FSC:6850
NIIN:00N011523
MSDS Number: BJFHC

MADISON CHEMICAL CO,INC

STATE ROAD 62
MADISON, IN 47250
US

Emergency Phone: 812-273-6000 WK DAYS;812-(SUP DATA)

Info Phone: 812-273-6000 WEEK DAYS

Preparer: STEVEN T HALE

Cage: 60142

MADISON CHEMICAL CO INC

125 MADISON, IN 47250 US

Cage: 60142

PHOSPHORIC ACID (SARA III)

CAS: 7664-38-2

RTECS: TB6300000

Fraction By Weight: 55% MAX

OSHA PEL 1 MG/M3/3 STEL

ACGIH TLV: 1 MG/M3/3 STEL; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES BURNS TO SKIN,EYES AND
ALIMENTARY CANAL.HARMFUL IF SWALLOWED.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES/SKIN/INHALATION:CONTACTED AREAS MAY
EXHIBIT IRRITATION AND CAN BE BURNED.INGESTION:CAUSES BURNS TO
ALIMENTARY CANAL.HARMFUL IF SWALLOWED.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:IMMED FLUSH W/ LARGE QUANTITIES OF COOL WATER
CONTINUOUSLY FOR AT LEAST 15 MIN.CALL MD.SKIN:IMMED FLUSH W/ LARGE
QUANTITIES OF COOL WATER CONTINUOUSLY FOR AT LEAST 15 MIN.CALL
MD.REMOVE CONTAMINA TED CLOTHING & SHOES.INGEST:DO NOT INDUCE
VOMITING.GIVE WATER.NEVER GIVE ANYTHING BY MOUTH TO AN UNCON
PERSON.CALL MD.INHAL:REMOVE TO FRESH AIR.IF SYMP ARE
PRESENT/DEVELOP,GET MEDICAL ATTENTION.

Flash Point Method:TOC
Flash Point:NONE TO BOILING
Extinguishing Media:AS APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .WILL LIBERATE FLAMMABLE HYDROGEN GAS UPON
CONTACT WITH MANY METALS.
Unusual Fire/Explosion Hazard:HAZARDOUS DECOMPOSITION
PRODUCTS:PHOSPHORUS PENTOXIDE.

Spill Release Procedures:CONTAIN LIQUID SPILLS WITH SAND AND ABSORB ON
SODA ASH.DISPOSE WITH SOLID WASTES.FLUSH REMAINDER TO DRAIN WITH
WATER.
Neutralizing Agent:N/K

Handling and Storage Precautions:NORMAL FOR ACIDS.ALWAYS ADD ACIDS TO
WATER;NEVER ADD WATER TO ACID.
Other Precautions:FOR INDUSTRIAL USE ONLY.KEEP OUT OF REACH OF
CHILDREN.HARMFUL IF SWALLOWED.CONTAINS PHOSPHORIC ACID.

Respiratory Protection:USE NIOSH/MSHA APPROVED INORGANIC ACID VAPOR
RESPIRATOR FOR AREAS WHERE AIRBORNE EXPOSURE IS EXCESSIVE.
Ventilation:USE GOOD VENTILATION.LOCAL EXHAUST IS RECOMMENDED IF TLV'S
ARE EXCEEDED.
Protective Gloves:NITRILE RUBBER OR NEOPRENE.
Eye Protection:GOGGLES AND FACESHIELD NECESSARY.
Other Protective Equipment:RUBBER APRON & BOOTS REQUIRED & OTHER EQUIP
AS NEC TO AVOID CONTACT.EYEWASH FACILITY & EMER SHOWER IN CLOSE
PROXIMITY.
Work Hygienic Practices:WASH CONTAM CLOTHING AND SHOES THOROUGHLY IN
SOAP & WATER;RINSE REPEATEDLY IN CLEAN WATER & DRY BEFORE REUSE.
Supplemental Safety and Health
MFR EMER TEL NO:265-2703,812-273-6213 EVENINGS & WEEKENDS.ROUTES OF
ENTRY:EYES (MFR);INGESTION .PH:1.0-1.2 (100%);1.5-1.7 (1% BY
VOLUME).

Boiling Pt:B.P. Text:236F,113C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Spec Gravity:1.36 (WATER=1)
pH:SUP DA
Evaporation Rate & Reference:1.0 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,WATER-WHITE,VISCOUS LIQUID WITH MILD ODOR.

Stability Indicator/Materials to Avoid:YES
ALKALINE MATERIALS,ACTIVE METALS SUCH AS ALUMINUM,ZINC,IRON,ETC.
Hazardous Decomposition Products:PHOSPHORUS PENTOXIDE.FLAMMABLE
HYDROGEN GAS UPON CONTACT WITH MANY METALS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .NORMAL FOR
ACIDIC,PHOSPHATE-CONTAINING WASTES.MAY REQUIRE PH ADJUSTMENT FOR
NEUTRALIZATION.LISTED:SARA TITLE III,SECTION 313.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.